Barcelona captain Raphinha scored two goals, leading his side to a resounding 5-1 victory over Feyenoord in their opening Champions League fixture. Meanwhile, Ermedin Demirovic's hat-trick secured a 3-1 win for VfB Stuttgart against Viking Stavanger.
Defending champions PSG will face Barcelona and Manchester City in the Champions League league phase, while Real Madrid meet Inter Milan and Arsenal in marquee clashes.
Chelsea survived the dismissal of captain John Terry to eliminate holders Barcelona 3-2 on aggregate and clinch a place in the Champions League final after an action-packed last-four clash on Tuesday in which Lionel Messi missed a penalty.
Last year's finalists Juventus will face-off against Bundesliga champs Bayern.
Arsenal forward Stina Blackstenius struck a late winner as the London team shocked holders Barcelona 1-0 on Saturday to claim their second Women's Champions League title and first in 18 years to the delight of their 5,000 travelling fans.
The winners of the tie will face Real Sociedad or Athletic Bilbao in the final. Real Sociedad hold a 1-0 advantage ahead of their second leg in San Sebastian on March 4.
FC Barcelona hammered Newcastle United F.C. 7-2 to reach the Champions League quarter-finals, while Liverpool F.C., Bayern Munich and Atltico Madrid also advanced.
Barcelona came from an early goal down to beat Real Madrid 5-2 in the Spanish Super Cup final on Sunday
Barcelona and Lionel Messi can write new chapters in the record books on Tuesday if they are able to break out of the straightjacket imposed on them by AC Milan and reach the Champions League semi-finals.
Tito Vilanova was still Pep Guardiola's Barcelona assistant when he hit the headlines last August after Real Madrid coach Jose Mourinho jabbed him in the eye during a touchline scuffle in the Spanish Super Cup.
Seemingly rudderless and leaderless, Barcelona have little time to find solutions to their dip in form but they have a chance to lift morale when they visit a distracted Real Madrid in La Liga on Saturday.
Barcelona need to be more efficient in front of goal and iron out defensive lapses if they are to beat Real Madrid in the King's Cup last four, assistant coach Jordi Roura and midfielder Cesc Fabregas said on Monday.
Bayer Leverkusen face what looks to be the near-impossible task of putting three goals past Barcelona at the Nou Camp on Wednesday and to do so they will need to dethrone the undisputed passing kings of Europe.
LaLiga leaders Real Madrid's pursuit of a record-extending 36th Spanish title
Holders Barcelona will play Premier League leaders Arsenal in the last 16 of the Champions League, 10 years after the sides faced each other in the final, following Monday's draw for the first knockout stage.
Real Madrid are on the verge of reaching the King's Cup quarter-finals after winning 3-0 at Numancia on Thursday while holders Barcelona still have work to do after being held to a 1-1 draw at Celta Vigo.
Mouth-watering matches lined up as PSG to face Bayern and Barcelona in Champions League opening stage.
IMAGES from the UEFA Champions League matches played on Wednesday.
Barcelona captain Raphinha scored twice as they returned to winning ways in LaLiga for the first time in a month with a 5-1 victory at Mallorca on Tuesday.
'We've been talking during this week and now it's the right moment to announce it.'
Barca, chasing a third consecutive Spanish title, are on 76 points after 35 games while Real Madrid are top with 77 and can restore their four-point advantage when they host Alaves on Friday.
Zlatan Ibrahimovic's second-half equaliser earned holders Barcelona a 1-1 draw at VfB Stuttgart in their Champions League last-16 first leg on Tuesday.
An error from Barcelona goalkeeper Victor Valdes allowed Real Madrid to grab a late second goal, which kept them alive in the Spanish Super Cup, after Barcelona ran out 3-2 winners in Thursday's first leg.
Barcelona closed in on the LaLiga title as they picked up a 1-0 win over Osasuna and holders Real Madrid went down to
The following is the draw for the Champions League last 16 which was held in Nyon on Monday:
The two-legged ties will be played from February 16.
Lionel Messi scored twice as King's Cup holders Barcelona moved comfortably into the quarter-finals by thrashing Celta Vigo 5-0 at the Nou Camp in their last 16 second leg game on Thursday.
Barcelona and Sevilla claimed the final two places in the King's Cup semi-finals on Thursday, Barca knocking out city rivals Espanyol 3-2 and Sevilla coming through on away goals against holders Valencia. Sevilla, the 2007 winners, will play Athletic Bilbao for a place in May's final in Valencia, while Barca take on Real Mallorca.
Thiago Silva powered home a header in the second minute of stoppage time to steal a 2-2 draw for AC Milan at holders Barcelona in the heavyweight pair's Champions League Group H opener on Tuesday.
Holders Barcelona reached the King's Cup semi-finals with a 2-0 win over Espanyol on Thursday to overcome a first-leg deficit on a night when new signing Philippe Coutinho made his debut.
Sporting marked the final home game of coach Ruben Amorim's reign in stunning fashion as Viktor Gyokeres' hat-trick saw them come from behind to thrash Manchester City 4-1 and maintain their superb start to the Champions League on Tuesday.
Images from the UEFA Champions League matches played on Tuesday night.
The King's Cup final between record winners Barcelona and Athletic Bilbao on May 30 will be held at Barca's Nou Camp.
Images from the football matches played across Europe on Sunday.
Holders Barcelona will begin their defence of the Champions League with a home match against AC Milan after the two old rivals were drawn in the same group on Thursday.
It was Messi's 56th converted penalty in La Liga and saw him draw level with Hugo Sanchez as the league's second-top penalty taker, behind record holder Cristiano Ronaldo on 61.
Barcelona and Real Madrid are on course for a King's Cup final showdown after Spain's two dominant teams recorded convincing home wins in their semi-final first legs on Wednesday.
Tuesday's match was the latest masterclass from the South American trio, known in Spain as 'MSN', whose goals have put Barca on the brink of repeating 2009's treble of Champions League and Spanish league and Cup triumphs, the only time a La Liga club have achieved the feat.
Barcelona coach Luis Enrique has decided to rest Lionel Messi, Neymar and most of his regulars for the King's Cup last 16, second leg match at Elche later on Thursday.
Lionel Messi netted a brilliant first-half hat-trick and added a late fourth to fire holders Barcelona past Arsenal into the last four of the Champions League on Tuesday.
